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Volumetric Behaviour of the Ternary System (Methyl Tert-butyl ether + Methylbenzene + Butan-1-ol) and Its Binary sub-System (Methyl Tert-Butyl Ether + Butan-1-ol) within the Temperature Range (298.15–328.15) K
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SYSNO ASEP 0445172 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Volumetric Behaviour of the Ternary System (Methyl Tert-butyl ether + Methylbenzene + Butan-1-ol) and Its Binary sub-System (Methyl Tert-Butyl Ether + Butan-1-ol) within the Temperature Range (298.15–328.15) K Tvůrce(i) Morávková, Lenka (UCHP-M) RID, SAI
Troncoso, J. (ES)
Škvorová, M. (CZ)
Havlica, Jaromír (UCHP-M) RID, ORCID, SAI
Petrus, P. (CZ)
Sedláková, Zuzana (UCHP-M) RID, ORCID, SAIZdroj.dok. Journal of Chemical Thermodynamics. - : Elsevier - ISSN 0021-9614
Roč. 90, NOV 2015 (2015), s. 59-70Poč.str. 12 s. Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova methylbenzene ; density ; methyl-tert-butyl ether Vědní obor RIV CI - Průmyslová chemie a chemické inženýrství CEP GAP105/12/0664 GA ČR - Grantová agentura ČR LD14094 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy Institucionální podpora UCHP-M - RVO:67985858 UT WOS 000359308800009 EID SCOPUS 84933509655 DOI 10.1016/j.jct.2015.06.009 Anotace Values of the density and speed of sound were measured for the ternary system (methyl tert-butyl ether + methylbenzene + butan-1-ol) within the temperature range (298.15 to 328.15) K at atmospheric pressure by a vibrating-tube densimeter DSA 5000. Two binary sub-systems were studied and published previously while the binary sub-system (methyl tert-butyl ether + butan-1-ol) is a new study in this work. Excess molar volume, adiabatic compressibility, and isobaric thermal expansivity were calculated from the experimental values of density and speed of sound. The excess quantities were correlated using the Redlich–Kister equation. The experimental excess molar volumes were analyzed by means of both the Extended Real Associated Solution (ERAS) model and the Peng–Robinson equation of state. The novelty of this work is the qualitative prediction of ternary excess molar volumes for the system containing auto-associative compound and two compounds that can hetero-associate. The combination of the ERAS model and Peng–Robinson equation of state could help to qualitatively estimate the real behavior of the studied systems because the experimental results lie between these two predictions. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2016
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