Počet záznamů: 1  

Preparation of conducting polysiloxane/polyaniline composites

  1. 1.
    SYSNO ASEP0445036
    Druh ASEPJ - Článek v odborném periodiku
    Zařazení RIVJ - Článek v odborném periodiku
    Poddruh JČlánek ve WOS
    NázevPreparation of conducting polysiloxane/polyaniline composites
    Tvůrce(i) Depa, Katarzyna (UMCH-V)
    Strachota, Adam (UMCH-V) RID, ORCID
    Stejskal, Jaroslav (UMCH-V) RID, ORCID, SAI
    Bober, Patrycja (UMCH-V) RID, ORCID, SAI
    Cimrová, Věra (UMCH-V) RID, ORCID
    Prokeš, J. (CZ)
    Trchová, Miroslava (UMCH-V) RID, ORCID
    Šlouf, Miroslav (UMCH-V) RID, ORCID
    Hodan, Jiří (UMCH-V)
    Zdroj.dok.Journal of Applied Polymer Science. - : Wiley - ISSN 0021-8995
    Roč. 132, č. 35 (2015), 42429_1-42429_11
    Poč.str.11 s.
    Jazyk dok.eng - angličtina
    Země vyd.US - Spojené státy americké
    Klíč. slovacoatings ; composites ; conducting polymers
    Vědní obor RIVJI - Kompozitní materiály
    CEPGAP107/12/2445 GA ČR - Grantová agentura ČR
    GA13-26542S GA ČR - Grantová agentura ČR
    Institucionální podporaUMCH-V - RVO:61389013
    UT WOS000356812400007
    EID SCOPUS84933180348
    DOI10.1002/app.42429
    AnotacePolysiloxane/polyaniline microcomposites were prepared, in which polyaniline particles act as filler, thus combining the mechanical properties of polysiloxane matrix with conductivity of polyaniline. Two syntheses were evaluated: (1) homogeneous dispersion of a polyaniline colloid in the reaction mixture from which the polysiloxane matrix subsequently formed, and (2) the blending of previously prepared dry polyaniline particles with a liquid oligomeric siloxane resin followed by cure (“heterogeneous method”). Both methods lead to composites with evenly distributed filler. Electrical conductivity was achieved above 40 wt % of polyaniline, which is better obtained by the “heterogeneous” method. During the composite cure, the polyaniline particles, which are softer than the matrix, act as a catalyst and cause more efficient matrix crosslinking, thus leading to somewhat raised moduli. Although particulate fillers usually deteriorate the impact toughness, in the case of the prepared composites, the impact toughness was preserved due to the softer consistence of the filler, which hinders crack propagation.
    PracovištěÚstav makromolekulární chemie
    KontaktEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Rok sběru2016
Počet záznamů: 1  

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