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Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins
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SYSNO ASEP 0431040 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins Tvůrce(i) Strachota, Adam (UMCH-V) RID, ORCID
Rodzen, Krzysztof (UMCH-V)
Ribot, F. (FR)
Trchová, Miroslava (UMCH-V) RID, ORCID
Steinhart, Miloš (UMCH-V) RID
Starovoytova, Larisa (UMCH-V) RID
Pavlova, Ewa (UMCH-V) RIDZdroj.dok. Macromolecules. - : American Chemical Society - ISSN 0024-9297
Roč. 47, č. 13 (2014), s. 4266-4287Poč.str. 22 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova nanocomposite ; hybrid ; stannoxane Vědní obor RIV CD - Makromolekulární chemie CEP GAP108/11/2151 GA ČR - Grantová agentura ČR Institucionální podpora UMCH-V - RVO:61389013 UT WOS 000338806400016 EID SCOPUS 84903955055 DOI 10.1021/ma500507j Anotace Hybrid organic–inorganic epoxies containing the heavier POSS homologue, n-butylstannoxane dodecamer, incorporated as an inert block, as a linear unit, and as a network junction were prepared. This nanometer-sized inorganic cage is especially attractive because of its chemical reactivity (besides mechanical matrix reinforcement). It can undergo oxidative cross-linking reactions with the matrix, or at elevated temperature in the absence of air, it can oligomerize to larger nanodomains, thus generating additional chemical cross-links. The influences of the bonding situation of the stannoxane cages on the hybrid resins’ morphology, mechanical properties, and on the cages’ chemical activity were studied. Pracoviště Ústav makromolekulární chemie Kontakt Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Rok sběru 2015
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