Počet záznamů: 1
The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins
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SYSNO ASEP 0429923 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins Tvůrce(i) Žáček, Petr (UOCHB-X) RID
Kaluža, Luděk (UCHP-M) RID, ORCID, SAI
Karban, Jindřich (UCHP-M) RID, ORCID, SAI
Storch, Jan (UCHP-M) RID, ORCID, SAI
Sýkora, Jan (UCHP-M) RID, ORCID, SAIZdroj.dok. Reaction Kinetics Mechanism and Catalysis. - : Springer - ISSN 1878-5190
Roč. 112, č. 2 (2014), s. 335-346Poč.str. 12 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova hydrodesulfurization ; olefin hydrogenation ; branched cyclic olefins Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEP GAP106/11/0902 GA ČR - Grantová agentura ČR Institucionální podpora UCHP-M - RVO:67985858 ; UOCHB-X - RVO:61388963 UT WOS 000339378700004 DOI 10.1007/s11144-014-0709-z Anotace In the study of the simultaneous hydrodesulfurization of 1-benzothiophene and the olefin hydrogenation of 1-methylcyclohex-1-ene (1-MCH), we encountered a rearrangement of 1-MCH during the first step of catalytic hydrogenation, which yielded various branched cyclic olefins; mainly ethylcyclopentene and dimethylcyclopentene isomers. The volatile isomerization products were isolated directly from the diluted reaction mixture via the combination of chromatographic techniques including preparative gas chromatography, and were undoubtedly assigned by NMR spectroscopy. The precise identification of the isomerization products was required for a detailed kinetic study. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2015
Počet záznamů: 1