Počet záznamů: 1
Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes
- 1.0355604 - ÚOCHB 2011 RIV DE eng J - Článek v odborném periodiku
Eignerová, Barbara - Janoušek, Zbyněk - Dračínský, Martin - Kotora, M.
Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes.
Synlett. -, č. 6 (2010), s. 885-888. ISSN 0936-5214. E-ISSN 1437-2096
Grant CEP: GA MŠMT(CZ) LC06077; GA MŠMT LC523
Grant ostatní: GA MŠk(CZ) LC06070
Program: LC
Výzkumný záměr: CEZ:AV0Z40550506; CEZ:AV0Z40320502
Klíčová slova: metathesis * perfluoroalkylation * ruthenium * carboranes * metallacarboranes
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.447, rok: 2010
A ruthenium complex (Hoveyda–Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31–53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes.
Trvalý link: http://hdl.handle.net/11104/0194338
Počet záznamů: 1