Počet záznamů: 1
Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase
- 1.0363624 - ÚOCHB 2012 RIV US eng J - Článek v odborném periodiku
Ducháčková, L. - Schröder, Detlef - Roithová, J.
Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase.
Inorganic Chemistry. Roč. 50, č. 7 (2011), s. 3153-3158. ISSN 0020-1669. E-ISSN 1520-510X
Grant CEP: GA ČR GA203/08/1487
Výzkumný záměr: CEZ:AV0Z40550506
Klíčová slova: acetate * infrared multiphoton dissociation * mass spectrometry * zinc
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 4.601, rok: 2011
The effect of different modes of the carboxylato ligands on the reactivity of gaseous zinc-acetate complexes is investigated by infrared multiphoton dissociation spectroscopy. In [(Imi)nZn(CH3COO)]+ complexes (Imi = imidazole, n = 1-3) the coordination changes from bi- to monodentate upon coordination of the third imidazole ligand ("carboxylate shift").
Trvalý link: http://hdl.handle.net/11104/0006535
Počet záznamů: 1