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The natural chlorine cycle - Formation of the carcinogenic and greenhouse gas compound chloroform in drinking water reservoirs

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    0461919 - ÚEB 2017 RIV GB eng J - Článek v odborném periodiku
    Forczek, Sándor - Pavlík, Milan - Holík, Josef - Rederer, L. - Ferenčík, M.
    The natural chlorine cycle - Formation of the carcinogenic and greenhouse gas compound chloroform in drinking water reservoirs.
    Chemosphere. Roč. 157, AUG (2016), s. 190-199. ISSN 0045-6535
    Grant CEP: GA ČR GA13-11101S
    Institucionální podpora: RVO:61389030
    Klíčová slova: Climate relevant compounds * Trichloromethane * Adsorbable organohalogens
    Kód oboru RIV: EF - Botanika
    Impakt faktor: 4.208, rok: 2016

    Chlorine cycle in natural ecosystems involves formation of low and high molecular weight organic compounds of living organisms, soil organic matter and atmospherically deposited chloride. Chloroform (CHCl3) and adsorbable organohalogens (AOX) are part of the chlorine cycle. We attempted to characterize the dynamical changes in the levels of total organic carbon (TOC), AOX, chlorine and CHCl3 in a drinking water reservoir and in its tributaries, mainly at its spring, and attempt to relate the presence of AOX and CHCl3 with meteorological, chemical or biological factors.

    Water temperature and pH influence the formation and accumulation of CHCl3 and affect the conditions for biological processes, which are demonstrated by the correlation between CHCl3 and Sigma AOX/Cl- ratio, and also by CHCl3/Sigma AOX, CHCl3/AOX(LMW), CHCl3/Sigma TOC, CHCl3/TOCLMW and CHCl3/Cl- ratios in different microecosystems (e.g. old spruce forest, stagnant acidic water, humid and warm conditions with high biological activity). These processes start with the biotransformation of AOX from TOC, continue via degradation of AOX to smaller molecules and further chlorination, and finish with the formation of small chlorinated molecules, and their subsequent volatilization and mineralization. The determined concentrations of chloroform result from a dynamic equilibrium between its formation and degradation in the water; in the Hamry water reservoir, this results in a total amount of 0.1-0.7 kg chloroform and 5.2-15.4 t chloride. The formation of chloroform is affected by Cl- concentration, by concentrations and ratios of biogenic substrates (TOC and AOX), and by the ratios of the substrates and the product (feedback control by chloroform itself).
    Trvalý link: http://hdl.handle.net/11104/0261475
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