Theoretical Background for Predicting the Properties of Petroleum Fluids via Group Contribution Methods

0383287 - ÚCHP 2013 RIV NL eng J - Článek v odborném periodiku
Bogdanić, Grozdana - Pavlíček, Jan - Wichterle, Ivan
Theoretical Background for Predicting the Properties of Petroleum Fluids via Group Contribution Methods.
Procedia Engineering. Roč. 42, SI (2012), s. 1873-1878. E-ISSN 1877-7058.
[International Congress of Chemical and Process Engineering CHISA 2012 and 15th Conference PRES 2012 /20./. Prague, 25.08.2012-29.08.2012]
Institucionální podpora: RVO:67985858
Klíčová slova: petroleum fluids * prediction * physico-chemical properties
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

The major problem encountered in the petroleum industry lies in the proper thermodynamic representation of rather complex fluids. In this work, the UNIFAC group contribution method for predicting the properties of such fluids has been exploited as a basis for their description in terms of model compounds. Standard thermodynamic procedures are used to estimate the critical properties, acentric factors, and molecular weights for the model compounds. In such a way, the already available generalized methods can be used for calculations of the phase equilibrium in complex petroleum mixtures.
Trvalý link: http://hdl.handle.net/11104/0216314