Počet záznamů: 1
Alkyloxycarbonyl group migration in furanosides
- 1.0382209 - ÚEB 2013 RIV GB eng J - Článek v odborném periodiku
Dvořáková, Marcela - Přibylová, Marie - Pohl, Radek - Migaud, M. E. - Vaněk, Tomáš
Alkyloxycarbonyl group migration in furanosides.
Tetrahedron. Roč. 68, č. 33 (2012), s. 6701-6711. ISSN 0040-4020. E-ISSN 1464-5416
Grant CEP: GA MŠMT(CZ) LH11048
Výzkumný záměr: CEZ:AV0Z50380511; CEZ:AV0Z40550506
Klíčová slova: Alkyloxycarbonyl group * Carbonate * Desilylation
Kód oboru RIV: DK - Kontaminace a dekontamin. půdy vč. pesticidů
Impakt faktor: 2.803, rok: 2012
A migration of methyloxycarbonyl group from secondary to primary hydroxyl was observed in furanosides (ribosides and xylosides) under usual desilylation conditions using tetrabutylammonium fluoride. The migration was studied further on several alkyloxycarbonyl furanosides under either basic or acidic conditions. As follows from C-13 labelling experiments and product distribution, the migration in xylosides, proceeds intramolecularly via six-membered cyclic carbonate, whereas in ribosides, the migration is intermolecular. Acidic conditions prevented the migration in ribosides whereas the migration in xylosides was circumvented under neutral conditions.
Trvalý link: http://hdl.handle.net/11104/0212498
Název souboru Staženo Velikost Komentář Verze Přístup 2012_Dvorakova_TETRAHEDRON_6701.pdf 4 1.1 MB Jiná povolen
Počet záznamů: 1