Počet záznamů: 1
Excess Properties of Aqueous Solutions: Hard Spheres versus Pseudo-Hard Bodies
- 1.0368376 - ÚCHP 2012 RIV GB eng J - Článek v odborném periodiku
Rouha, M. - Nezbeda, Ivo
Excess Properties of Aqueous Solutions: Hard Spheres versus Pseudo-Hard Bodies.
Molecular Physics. Roč. 109, č. 4 (2011), s. 613-617. ISSN 0026-8976. E-ISSN 1362-3028
Grant CEP: GA AV ČR IAA400720802
Výzkumný záměr: CEZ:AV0Z40720504
Klíčová slova: partial molar volume * primitive models * thermodynamic properties
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 1.819, rok: 2011
The effect of repulsive interactions (geometrical packing of molecules) on mixing properties is examined considering hard sphere solutes of different diameters in the hard sphere and pseudo-hard body solvents. It is shown that the fluid of pseudo-hard bodies, representing repulsive interactions in water, captures, without any parameter adjustment, the experimentally observed decrease of the partial molar volume of nonpolar solutes (hard spheres) at their low concentrations when compared to that in a nonpolar (hard sphere) solvent.
Trvalý link: http://hdl.handle.net/11104/0202740
Počet záznamů: 1