Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

Lyshchuk, Hlib; Chaudhary, A.; Luxford, Thomas Frederick Murray; Ranković, Miloš; Kočišek, Jaroslav; Fedor, Juraj; McElwee-White, L.; Nag, Pamir

doi:https://dx.doi.org/10.3762/bjnano.15.66

Počet záznamů: 1

Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

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SYSNO ASEP	0587757
Druh ASEP	J - Článek v odborném periodiku
Zařazení RIV	J - Článek v odborném periodiku
Poddruh J	Článek ve WOS
Název	Electron-induced ligand loss from iron tetracarbonyl methyl acrylate
Tvůrce(i)	Lyshchuk, Hlib (UFCH-W)_ORCID Chaudhary, A. (US) Luxford, Thomas Frederick Murray (UFCH-W) Ranković, Miloš (UFCH-W)_{ORCID, RID} Kočišek, Jaroslav (UFCH-W)_{RID, ORCID} Fedor, Juraj (UFCH-W)_ORCID McElwee-White, L. (US) Nag, Pamir (UFCH-W)_{ORCID, RID, SAI}
Zdroj.dok.	Beilstein Journal of Nanotechnology. - : Beilstein - Institut zur Foerderung der Chemischen Wissenschaften - ISSN 2190-4286 Roč. 15, JUL 2024 (2024), s. 797-807
Poč.str.	11 s.
Jazyk dok.	eng - angličtina
Země vyd.	DE - Německo
Klíč. slova	low-energy electrons ; set model chemistry ; mass-spectrometry ; fe(co)(5) ; attachment ; ionization ; electron collision ; focused electron beam-induced deposition (FEBID) ; FEBID precursor ; iron tetracarbonyl methyl acrylate
Vědní obor RIV	CF - Fyzikální chemie a teoretická chemie
Obor OECD	Physical chemistry
CEP	GX21-26601X GA ČR - Grantová agentura ČR
	EH22_008/0004558 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy
Způsob publikování	Open access
Institucionální podpora	UFCH-W - RVO:61388955
UT WOS	001263222200001
EID SCOPUS	85200348639
DOI	https://doi.org/10.3762/bjnano.15.66
Anotace	We probe the separation of ligands from iron tetracarbonyl methyl acrylate (Fe(CO)4(C4H6O2) or Fe(CO)4MA) induced by the interaction with free electrons. The motivation comes from the possible use of this molecule as a nanofabrication precursor and from the corresponding need to understand its elementary reactions fundamental to the electron-induced deposition. We utilize two complementary electron collision setups and support the interpretation of data by quantum chemical calculations. This way, both the dissociative ionization and dissociative electron attachment fragmentation channels are characterized. Considerable differences in the degree of precursor fragmentation in these two channels are observed. Interesting differences also appear when this precursor is compared to structurally similar iron pentacarbonyl. The present findings shed light on the recent electron-induced chemistry of Fe(CO)4MA on a surface under ultrahigh vacuum.
Pracoviště	Ústav fyzikální chemie J.Heyrovského
Kontakt	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Rok sběru	2025
Elektronická adresa	https://hdl.handle.net/11104/0354853

Počet záznamů: 1