Thick does the trick: genesis of ferroelectricity in 2D GeTe-rich (GeTe).sub.m./sub.(Sb.sub.2./sub.Te.sub.3./sub.).sub.n./sub. lamellae

0585018 - FZÚ 2025 RIV US eng J - Článek v odborném periodiku
Cecchi, S. - Momand, J. - Dragoni, D. - Abou El Kheir, O. - Fagiani, F. - Kriegner, Dominik - Rinaldi, C. - Arciprete, F. - Holý, V. - Kooi, B.J. - Bernasconi, M. - Calarco, R.
Thick does the trick: genesis of ferroelectricity in 2D GeTe-rich (GeTe)_m(Sb₂Te₃)_n lamellae.
Advanced Science. Roč. 11, č. 1 (2024), č. článku 2304785. E-ISSN 2198-3844
Grant CEP: GA ČR(CZ) GM22-22000M
Grant ostatní: AV ČR(CZ) LQ100102201
Program: Prémie Lumina quaeruntur
Institucionální podpora: RVO:68378271
Klíčová slova: 2D ferroelectrics * van der Waals * molecular beam epitaxy * phase-change materials * density functional theory calculations
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 15.1, rok: 2022
Způsob publikování: Open access

The possibility to engineer (GeTe)m(Sb2Te3)n phase-change materials to co-host ferroelectricity is extremely attractive. The combination of these functionalities holds great technological impact, potentially enabling the design of novel multifunctional devices. Here an experimental and theoretical study of epitaxial (GeTe)m(Sb2Te3)n with GeTe-rich composition is presented. These layered films feature a tunable distribution of (GeTe)m(Sb2Te3)1 blocks of different sizes. Breakthrough evidence of ferroelectric displacement in thick (GeTe)m(Sb2Te3)1 lamellae is provided. The density functional theory calculations suggest the formation of a tilted (GeTe)m slab sandwiched in GeTe-rich blocks. That is, the net ferroelectric polarization is confined almost in-plane, representing an unprecedented case between 2D and bulk ferroelectric materials. The ferroelectric behavior is confirmed by piezoresponse force microscopy and electroresistive measurements.
Trvalý link: https://hdl.handle.net/11104/0352787