Počet záznamů: 1
Nickel-Copper Oxide Catalysts Deposited on Stainless Steel Meshes by Plasma Jet Sputtering: Comparison with Granular Analogues and Synergistic Effect in VOC Oxidation
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SYSNO ASEP 0570352 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Nickel-Copper Oxide Catalysts Deposited on Stainless Steel Meshes by Plasma Jet Sputtering: Comparison with Granular Analogues and Synergistic Effect in VOC Oxidation Tvůrce(i) Jirátová, Květa (UCHP-M) RID, ORCID, SAI
Soukal, Petr (FZU-D)
Kapran, Anna (FZU-D) ORCID
Babii, T. (CZ)
Balabánová, Jana (UCHP-M) RID, ORCID, SAI
Koštejn, Martin (UCHP-M) RID, SAI, ORCID
Čada, Martin (FZU-D) RID, ORCID, SAI
Maixner, J. (CZ)
Topka, Pavel (UCHP-M) RID, ORCID, SAI
Hubička, Zdeněk (FZU-D) RID, ORCID, SAI
Kovanda, F. (CZ)Číslo článku 595 Zdroj.dok. Catalysts. - : MDPI
Roč. 13, č. 3 (2023)Poč.str. 21 s. Jazyk dok. eng - angličtina Země vyd. CH - Švýcarsko Klíč. slova plasma jet sputtering ; thin film ; nickel-copper oxides Obor OECD Chemical process engineering CEP GA21-04477S GA ČR - Grantová agentura ČR Způsob publikování Open access Institucionální podpora UCHP-M - RVO:67985858 ; FZU-D - RVO:68378271 UT WOS 000954163900001 EID SCOPUS 85151478593 DOI 10.3390/catal13030595 Anotace A novel method for the preparation of Ni-Cu oxide catalysts—deposition on stainless steel meshes using hollow cathode plasma jet sputtering—was studied. This method allows the preparation of thin oxide films. Consequently, the whole volume of the active phase is readily accessible for the reactants and can be employed in the catalytic reaction due to the negligible effect of internal diffusion. As a result, the activity of our sputtered catalyst was seven times higher in ethanol oxidation and 61 times higher in toluene oxidation than that of the corresponding granular catalyst. Moreover, due to stainless steel meshes used as a catalyst support, the pressure drop across the catalyst bed was lower. Finally, the catalytic activity of the sputtered Ni-Cu oxide catalyst with Ni:Cu molar ratio of 1:1 in ethanol oxidation was 1.7 times higher than that of the commercial EnviCat® VOC-1544 catalyst, while the amount of the active phase in the catalyst bed was 139 times lower. The outstanding performance of the Ni0.5Cu0.5 catalyst was ascribed to the synergistic effect between the copper and nickel components. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2024 Elektronická adresa https://www.mdpi.com/2073-4344/13/3/595
Počet záznamů: 1