Počet záznamů: 1
Phase transitions and physical properties of the mixed valence iron phosphate Fe.sub.3./sub.(PO.sub.3./sub.OH).sub.4./sub.(H.sub.2./sub.O).sub.4./sub.
- 1.0565404 - FZÚ 2023 RIV CH eng J - Článek v odborném periodiku
Poienar, M. - Gutmann, M.J. - Pascut, G.L. - Petříček, Václav - Stenning, G. - Vlazan, P. - Sfirloagă, P. - Paulmann, C. - Tolkiehn, M. - Manuel, P. - Veber, P.
Phase transitions and physical properties of the mixed valence iron phosphate Fe3(PO3OH)4(H2O)4.
Materials. Roč. 15, č. 22 (2022), č. článku 8059. E-ISSN 1996-1944
Institucionální podpora: RVO:68378271
Klíčová slova: crystal structures * structural and magnetic phase transitions * mixed valence * single crystal x-ray diffraction * neutron powder diffraction * density functional theory
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 3.4, rok: 2022
Způsob publikování: Open access
Iron phosphate materials have attracted a lot of attention due to their potential as cathode materials for lithium-ion rechargeable batteries. It has been shown that lithium insertion or extraction depends on the Fe mixed valence and reduction or oxidation of the Fe ions' valences. In this paper, we report a new synthesis method for the Fe3(PO3OH)4(H2O)4 mixed valence iron phosphate. In addition, we perform temperature-dependent measurements of structural and physical properties in order to obtain an understanding of electronic–structural interplay in this compound.
Trvalý link: https://hdl.handle.net/11104/0339038
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