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One-Pot Hydrogen Cyanide-Based Prebiotic Synthesis of Canonical Nucleobases and Glycine Initiated by High-Velocity Impacts on Early Earth
- 1.0536887 - ÚFCH JH 2021 RIV US eng J - Článek v odborném periodiku
Ferus, Martin - Rimmer, P. - Cassone, G. - Knížek, Antonín - Civiš, Svatopluk - Šponer, Judit E. - Ivanek, Ondřej - Šponer, Jiří - Saeidfirozeh, Homa - Kubelík, Petr - Dudžák, R. - Petera, Lukáš - Juha, L. - Pastorek, Adam - Křivková, Anna - Krůs, M.
One-Pot Hydrogen Cyanide-Based Prebiotic Synthesis of Canonical Nucleobases and Glycine Initiated by High-Velocity Impacts on Early Earth.
Astrobiology. Roč. 20, č. 12 (2020), s. 1476-1488. ISSN 1531-1074. E-ISSN 1557-8070
Grant CEP: GA ČR GA19-03314S; GA MŠMT EF16_019/0000778
Institucionální podpora: RVO:61388955 ; RVO:68081707
Klíčová slova: high-power laser * induced dielectric-breakdown * high-energy chemistry * chemical evolution * organic-synthesis * adenine synthesis * amino-acids * miller-urey * formamide * purine * Extraterrestrial objects impacts * Origin of life * Hydrogen cyanide * Primitive Earth atmosphere
Obor OECD: Physical chemistry; Physical chemistry (BFU-R)
Impakt faktor: 4.335, rok: 2020
Způsob publikování: Omezený přístup
Chemical environments of young planets are assumed to be significantly influenced by impacts of bodies lingering after the dissolution of the protoplanetary disk. We explore the chemical consequences of impacts of these bodies under reducing planetary atmospheres dominated by carbon monoxide, methane, and molecular nitrogen. Impacts were simulated by using a terawatt high-power laser system. Our experimental results show that one-pot impact-plasma-initiated synthesis of all the RNA canonical nucleobases and the simplest amino acid glycine is possible in this type of atmosphere in the presence of montmorillonite. This one-pot synthesis begins withde novoformation of hydrogen cyanide (HCN) and proceeds through intermediates such as cyanoacetylene and urea.
Trvalý link: http://hdl.handle.net/11104/0314639
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