Počet záznamů: 1
Pillaring of layered zeolite precursors with ferrierite topology leading to unusual molecular sieves on the micro/mesoporous border
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SYSNO ASEP 0506560 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Pillaring of layered zeolite precursors with ferrierite topology leading to unusual molecular sieves on the micro/mesoporous border Tvůrce(i) Roth, W. J. (PL)
Gil, B. (PL)
Mayoral, A. (ES)
Grzybek, J. (PL)
Korzeniowska, A. (PL)
Kubů, Martin (UFCH-W) RID
Makowski, W. (PL)
Čejka, Jiří (UFCH-W) RID, ORCID, SAI
Olejniczak, Z. (PL)
Mazur, M. (CZ)Zdroj.dok. Dalton Transactions. - : Royal Society of Chemistry - ISSN 1477-9226
Roč. 47, č. 9 (2018), s. 3029-3037Poč.str. 9 s. Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova quasi-equilibrated thermodesorption ; fer-type zeolite ; intercalation chemistry ; topotactic condensation ; n-nonane ; silicate Vědní obor RIV CF - Fyzikální chemie a teoretická chemie Obor OECD Physical chemistry CEP GA17-01440S GA ČR - Grantová agentura ČR Způsob publikování Omezený přístup Institucionální podpora UFCH-W - RVO:61388955 UT WOS 000428840900020 EID SCOPUS 85042654703 DOI 10.1039/c7dt03718j Anotace Layered zeolite materials with FER layer topology can produce various condensed and expanded structures including zeolite frameworks, FER and CDO, their interlayer expanded forms (IEZ), and organic-intercalated and pillared derivatives. This work concerns pillaring of the surfactant-swollen derivative with a gallery height of ca. 2.5 nm between layers by treatment with tetraethylorthosilicate (TEOS) at room and elevated temperatures. The materials obtained at 100 degrees C and higher showed unusual properties including 2 nm pores on the micro/mesoporous border and disordered layer packing indicated by the absence of distinct low angle interlayer peaks at d-spacing >3 nm (similar to 3 degrees 2 theta Cu K alpha radiation) in the X-ray diffraction pattern (XRD). TEOS treatment at room temperature produced a pillared molecular sieve with the expected mesoporous characteristics, namely a pore size of around 3 nm and a high intensity low angle (001) peak at 2.3 degrees 2 theta, and a d-spacing of 3.8 nm, in the XRD. The characterization aiming to elucidate the nature of the obtained unusual products included gas adsorption isotherms, aberration corrected (Cs-corrected) Scanning Transmission Electron Microscopy (STEM) studies and Si-29 solid state NMR. BET surface area values decreased with the temperature of TEOS treatment from approximately 1200 m(2) g(-1) to similar to 900 and 600 m(2) g(-1), at room temperature, 100 degrees C, and 120 degrees C, respectively. The Si-29 solid state NMR revealed the presence of both Q(3) ((SiO)(3)SiOX, X = H or minus charge) and Q(4) ((SiO)(4)Si) centers giving separated signals up to the pillaring step. After pillaring at 100 degrees C and calcination, the nominal intensity ratios Q(4) : Q(3) were 2.17 and 2.61 but the signals were merged into one broad peak indicating the structural heterogeneity of Si-O coordination. The microscopy showed the presence of FER layers in the samples but the overall structure and composition were not well-defined. The observed unusual disorganization and possible partial degradation of layers during pillaring may result from the combination of high temperature, alkalinity (surfactant hydroxide) and siliceous composition of the layers. The obtained pillared products are of interest for the preparation of larger pore catalysts and sorbents or controlled drug delivery. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2020 Elektronická adresa http://hdl.handle.net/11104/0297793
Počet záznamů: 1