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S-(-)-1-phenyl ethyl ammonium(1+) sulphate and S-(-)-1-phenyl ethyl ammonium(1+) hydrogen phosphate 2.5 hydrate, preparation and characterization of crystallographic, optical and dielectric properties
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SYSNO ASEP 0437042 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název S-(-)-1-phenyl ethyl ammonium(1+) sulphate and S-(-)-1-phenyl ethyl ammonium(1+) hydrogen phosphate 2.5 hydrate, preparation and characterization of crystallographic, optical and dielectric properties Tvůrce(i) Cihelka, Jaroslav (UFCH-W)
Havlíček, D. (CZ)
Gyepes, R. (CZ)
Němec, I. (CZ)
Koleva, Z. (BG)Zdroj.dok. Journal of Molecular Structure. - : Elsevier - ISSN 0022-2860
Roč. 980, 1-3 (2010), s. 31-38Poč.str. 8 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova Chiral amines - salts ; Crystal structure ; IR and Raman spectroscopy Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000282108900006 EID SCOPUS 77956056431 DOI https://doi.org/10.1016/j.molstruc.2010.06.033 Anotace S-(-)-1-phenyl ethyl ammonium(1+) sulphate and S-(-)-1-phenyl ethyl ammonium(1+) hydrogen phosphate 2.5 hydrate were prepared at laboratory temperature by slow evaporation of aqueous solutions of a mixture of S-(-)-1-phenyl ethyl amine and H(2)SO(4) or H(3)PO(4) in a molar ratio of 2: 1. The chirality on the organic amine was retained during the preparation and the obtained substances crystallized in non-centrosymmetric space groups. S-(-)-1-phenyl ethyl ammonium (1+) sulphate crystallizes in a monoclinic crystal system, space group C2, a = 10.8050(5) angstrom, b = 6.1080(4) angstrom, c = 13.3430(8) angstrom, beta = 90.679(4)degrees, V= 880.54(9) angstrom(3), Z = 2, calculated density 1.284 g cm(-3). S-(-)-1-phenyl ethyl ammonium(1+) hydrogen phosphate 2.5 hydrate crystallizes in a monoclinic crystal system, space group P2(1), a = 16.7810(10) angstrom, b = 6.2870(2) angstrom. C = 19.7060(12) angstrom, beta = 109.160(2)degrees, V = 1963.86(18) angstrom(3), Z = 4, calculated density 1.303 g cm(-3). Space groups C2 and P2(1) belong amongst "polar" groups, that could exhibit interesting dielectric properties, which have been studied (dependence of the polarization on an external electric field or of the relative permittivity on the temperature), and generation of the second harmonic frequency. Both substances were further characterized by chemical analysis, X-ray structural and powder analysis, infrared and Raman spectroscopy and thermal analysis (DTA, TGA). (C) 2010 Elsevier B.V. All rights reserved. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2015
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