4,4´-Dimethyl-2,2´-[imidazolidine-1,3-diylbis(methylene)] diphenol

0384318 - FZÚ 2013 RIV DK eng J - Článek v odborném periodiku
Rivera, A. - Nerio, L.S. - Ríos-Motta, J. - Kučeráková, Monika - Dušek, Michal
4,4´-Dimethyl-2,2´-[imidazolidine-1,3-diylbis(methylene)] diphenol.
Acta Crystallographica Section E-Structure Reports Online. Roč. 68, Part 11 (2012), "o3172"-"sup7". ISSN 1600-5368. E-ISSN 2056-9890
Grant ostatní: AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Výzkumný záměr: CEZ:AV0Z10100521
Klíčová slova: single-crystal X-ray study * T = 120 K * mean δ(C–C) = 0.002 A * R factor = 0.033 * wR factor = 0.104 * data-to-parameter ratio = 14.0
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 0.347, rok: 2011

The imidazolidine ring in the title compound, C19H24N2O2, adopts a twist conformation and its mean plane (r.m.s. deviation = 0.19 A ) makes dihedral angles of 72.38 (9) and 71.64 (9) with the two pendant aromatic rings. The dihedral angle between the phenyl rings is 55.94 (8). The molecular structure shows the presence of two intramolecular O-H...N hydrogen bonds between the phenolic hydroxyl groups and N atoms with graph-set motif S(6). In the crystal, C-H...O hydrogen bonds lead to the formation of chains along the b-axis direction.
Trvalý link: http://hdl.handle.net/11104/0214013