Počet záznamů: 1
Organic Electrochemistry
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SYSNO ASEP 0181564 Druh ASEP M - Kapitola v monografii Zařazení RIV C - Kapitola v knize Název Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity Tvůrce(i) Ludvík, Jiří (UFCH-W) RID, ORCID
Cibulka, R. (CZ)Zdroj.dok. Organic Electrochemistry / Baizer M. M.. - Pennington : ECS, 2002 Rozsah stran s. 142-146 Poč.str. 5 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova ketoximes ; chelates ; electroreduction Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEP GA203/01/1093 GA ČR - Grantová agentura ČR Anotace Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes I-V and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2003
Počet záznamů: 1