Iron(II) versus Osmium(II) Oxidation in 1,1'-Bis(diorganophosphino)Ferrocene-Osmium(II) Complexes

Počet záznamů: 1

SYSNO ASEP	0181313
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Ostatní články
Title	Iron(II) versus Osmium(II) Oxidation in 1,1'-Bis(diorganophosphino)Ferrocene-Osmium(II) Complexes
Author(s)	Kaim, W. (DE) Sixt, T. (DE) Weber, M. (DE) Fiedler, Jan (UFCH-W)_{RID, ORCID}
Source Title	Journal of Organometallic Chemistry. - : Elsevier - ISSN 0022-328X 637-639, - (2001), s. 167-171
Number of pages	5 s.
Language	eng - English
Country	CH - Switzerland
Keywords	electrochemistry ; EPR spectroscopy ; osmium complexes
Subject RIV	CG - Electrochemistry
R&D Projects	OC D15.10 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
CEZ	AV0Z4040901 - UFCH-W
Annotation	The complexes of Os with p-cymene, chloride and bis(diphenylphosphino)- or bis(diethylphosphino)- or (diisopropylphosphino)ferrocene were synthesized and characterized by NMR, X-ray and spectroelectrochemically. Osmium(II)- ferrocenium species is formed on reversible one-electron oxidation. The second oxidation and the reduction are electrochemically irreversible.
Workplace	J. Heyrovsky Institute of Physical Chemistry
Contact	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Year of Publishing	2002

Počet záznamů: 1