Počet záznamů: 1
Cyanoethylation and (methoxycarbonyl)ethylation of icosahedral ortho-carborane derivatives at carbon vertices via Michael additions
- 1.0163270 - UACH-T 20013141 RIV CZ eng J - Článek v odborném periodiku
Plešek, Jaromír - Bačkovský, Jaroslav - Fusek, Jiří - Plzák, Zbyněk
Cyanoethylation and (methoxycarbonyl)ethylation of icosahedral ortho-carborane derivatives at carbon vertices via Michael additions.
Collection of Czechoslovak Chemical Communications. Roč. 66, č. 10 (2001), s. 1499-1507. ISSN 0010-0765
Grant CEP: GA ČR GA104/99/1096; GA MŠMT LB98233
Výzkumný záměr: CEZ:AV0Z4032918
Klíčová slova: boranes * carboranes * Michael additions
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 0.778, rok: 2001
The C-H vertices of ortho-carborane and its derivatives can be smoothly cyanoethylated with acrylonitrile in the presence of benzyl(triethyl)ammonium hydroxide in a two-phase system:dichloromethane/water or 1,2-dimethoxyethane/water. The reaction is highly specific and not transferable to its meta and para isomers.
Trvalý link: http://hdl.handle.net/11104/0060523
Počet záznamů: 1