Preparative-scale synthesis of nonacene

0552366 - ÚOCHB 2023 RIV GB eng J - Článek v odborném periodiku
Jančařík, Andrej - Holec, J. - Nagata, Y. - Šámal, Michal - Gourdon, A.
Preparative-scale synthesis of nonacene.
Nature Communications. Roč. 13, č. 1 (2022), č. článku 223. E-ISSN 2041-1723
Grant CEP: GA MŠMT(CZ) EF17_050/0008490
Institucionální podpora: RVO:61388963
Klíčová slova: on-surface synthesis * solid state * heptacene
Obor OECD: Organic chemistry
Impakt faktor: 16.6, rok: 2022
Způsob publikování: Open access
https://doi.org/10.1038/s41467-021-27809-0

During the last years we have witnessed progressive evolution of preparation of acenes with length up to dodecacene by on-surface synthesis in ultra-high vacuum or generation of acenes up to decacene in solid matrices at low temperatures. While these protocols with very specific conditions produce the acenes in amount of few molecules, the strategies leading to the acenes in large quantities dawdle behind. Only recently and after 70 years of synthetic attempts, heptacene has been prepared in bulk phase. However, the preparative scale synthesis of higher homologues still remains a formidable challenge. Here we report the preparation and characterisation of nonacene and show its excellent thermal and in-time stability.
Trvalý link: http://hdl.handle.net/11104/0327512