Počet záznamů: 1
Isotopic Tracing of Thallium Contamination in Soils Affected by Emissions from Coal-Fired Power Plants
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SYSNO ASEP 0464985 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Isotopic Tracing of Thallium Contamination in Soils Affected by Emissions from Coal-Fired Power Plants Tvůrce(i) Vaněk, A. (CZ)
Grösslová, Z. (CZ)
Mihaljevič, M. (CZ)
Trubač, J. (CZ)
Ettler, V. (CZ)
Teper, L. (PL)
Cabala, J. (PL)
Rohovec, Jan (GLU-S) RID, SAI
Zádorová, T. (CZ)
Penížek, V. (CZ)
Pavlů, L. (CZ)
Holubík, O. (CZ)
Němeček, K. (CZ)
Houška, J. (CZ)
Drábek, O. (CZ)
Ash, C. (CZ)Zdroj.dok. Environmental Science and Technology - ISSN 0013-936X
Roč. 50, č. 18 (2016), s. 9864-9871Poč.str. 8 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova environmental implications ; isotope ; fractionation ; combustion ; utility ; health ; oxides ; silver ; lead Vědní obor RIV DD - Geochemie Institucionální podpora GLU-S - RVO:67985831 UT WOS 000384037900009 EID SCOPUS 84988592724 DOI 10.1021/acs.est.6b01751 Anotace Here, for the first time, we report the thallium (Tl) isotope record in moderately contaminated soils with contrasting land management (forest and meadow soils), which have been affected by emissions from coal-fired power plants. Our findings clearly demonstrate that Tl of anthropogenic (high-temperature) origin with light isotope composition was deposited onto the studied soils, where heavier Tl (epsilon205Tl ∼ -1) naturally occurs. The results show a positive linear relationship (R2 = 0.71) between 1/Tl and the isotope record, as determined for all the soils and bedrocks, also indicative of binary Tl mixing between two dominant reservoirs. We also identified significant Tl isotope variations within the products from coal combustion and thermo-desorption experiments with local Tl-rich coal pyrite. Bottom ash exhibited the heaviest Tl isotope composition (epsilon205Tl ∼ 0), followed by fly ash (epsilon205Tl between -2.5 and -2.8) and volatile Tl fractions (epsilon205Tl between -6.2 and -10.3), suggesting partial Tl isotope fractionations. Despite the evident role of soil processes in the isotope redistributions, we demonstrate that Tl contamination can be traced in soils and propose that the isotope data represent a possible tool to aid our understanding of postdepositional Tl dynamics in surface environments for the future. Pracoviště Geologický ústav Kontakt Jana Popelková, popelkova@gli.cas.cz, Sabina Janíčková, Tel.: 233 087 272 Rok sběru 2017
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