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A new approach to model mixed hydrates
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SYSNO ASEP 0486183 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název A new approach to model mixed hydrates Tvůrce(i) Hielscher, S. (DE)
Vinš, Václav (UT-L) RID, ORCID
Jäger, A. (DE)
Hrubý, Jan (UT-L) RID, ORCID
Breitkopf, C. (DE)
Span, R. (DE)Celkový počet autorů 6 Zdroj.dok. Fluid Phase Equilibria. - : Elsevier - ISSN 0378-3812
Roč. 459, March (2018), s. 170-185Poč.str. 16 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova gas hydrate ; mixture ; modeling Vědní obor RIV BJ - Termodynamika Obor OECD Thermodynamics CEP GA17-08218S GA ČR - Grantová agentura ČR Institucionální podpora UT-L - RVO:61388998 UT WOS 000423002800017 EID SCOPUS 85038838696 DOI 10.1016/j.fluid.2017.12.015 Anotace A new model for mixed hydrates is proposed, which is intended for modeling the formation of mixed hydrates in carbon capture and storage (CCS)-relevant mixtures. The model is based on the model developed by Ballard and Sloan [A.L. Ballard, E.D. Sloan Jr., Fluid Phase Equilib. 194 (2002) 371-383], which itself is based on the statistical approach by van der Waals and Platteeuw [J.H. van der Waals, J.C. Platteeuw, Adv. Chem. Phys. 2 (1959) 1-57]. The model of Ballard and Sloan contains a considerable amount of adjustable parameters for mixed hydrates and comparatively complex mixing rules, especially for the molar volume of mixed hydrates. For the newly developed mixed hydrate model, a simple mixing rule for the volume is used, which does not contain any adjustable parameters. Comparisons of the new model with experimental data for mixed hydrates in the ternary system carbon dioxide + methane + water show better results than the model by Ballard and Sloan. Results for the quaternary system nitrogen + oxygen + argon + water are in good agreement with the available experimental data. Furthermore, as in our previous work focused on modeling hydrates of pure gases [Fluid Phase Equilib. 427 (2016) 268] and contrary to other published hydrate models, reference equations of state are used in order to model phases in equilibrium with hydrates. A comprehensive study on phase equilibria with up to four phases in equilibrium for ternary mixtures forming gas hydrates and other solid phases was carried out in this work. The obtained results demonstrate the capabilities of the proposed mixed hydrate model and developed phase equilibrium algorithms. Pracoviště Ústav termomechaniky Kontakt Marie Kajprová, kajprova@it.cas.cz, Tel.: 266 053 154 ; Jana Lahovská, jaja@it.cas.cz, Tel.: 266 053 823 Rok sběru 2019
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