IR Laser-Induced Thermolysis and UV Laser-Induced Photolysis of 1,3-Diethyldisiloxane: Chemical Vapour Deposition of Nanotextured Hydridoalkylsilicones

0166231 - UCHP-M 20013087 RIV GB eng J - Článek v odborném periodiku
Urbanová, Markéta - Bastl, Zdeněk - Šubrt, Jan - Pola, Josef
IR Laser-Induced Thermolysis and UV Laser-Induced Photolysis of 1,3-Diethyldisiloxane: Chemical Vapour Deposition of Nanotextured Hydridoalkylsilicones.
Journal of Materials Chemistry. Roč. 11, č. 6 (2001), s. 1557-1562. ISSN 0959-9428
Grant CEP: GA AV ČR IAA4072806
Klíčová slova: thermolysis * UV laser photolysis * composition
Kód oboru RIV: CH - Jaderná a kvantová chemie, fotochemie
Impakt faktor: 2.736, rok: 2001

IR laser thermolysis and UV laser photolysis of gaseous 1,3-diethyldisiloxane proceed via different mechanisms: the former involves 1,1-H2 and ethene elimination, whereas the latter is dominated by 1,1-H2 and ethane elimination. The difference plays an important role in determining the composition of the solid nanotextured films deposited from the gas phase.
Trvalý link: http://hdl.handle.net/11104/0001369