Počet záznamů: 1  

Erbium ion implantation into diamond-measurement and modelling of the crystal structure

  1. 1.
    SYSNO ASEP0484877
    Druh ASEPJ - Článek v odborném periodiku
    Zařazení RIVJ - Článek v odborném periodiku
    Poddruh JČlánek ve WOS
    NázevErbium ion implantation into diamond-measurement and modelling of the crystal structure
    Tvůrce(i) Cajzl, Jakub (URE-Y)
    Nekvindová, P. (CZ)
    Macková, Anna (UJF-V) RID, ORCID, SAI
    Malinský, Petr (UJF-V) RID, ORCID, SAI
    Sedmidubský, D. (CZ)
    Hušák, M. (CZ)
    Remeš, Zdeněk (FZU-D) RID, ORCID
    Varga, Marián (FZU-D) RID, ORCID
    Kromka, Alexander (FZU-D) RID, ORCID, SAI
    Bottger, R. (DE)
    Oswald, Jiří (FZU-D) RID, ORCID
    Celkový počet autorů12
    Zdroj.dok.Physical Chemistry Chemical Physics. - : Royal Society of Chemistry - ISSN 1463-9076
    Roč. 19, č. 8 (2017), s. 6233-6245
    Poč.str.13 s.
    Forma vydáníTištěná - P
    Jazyk dok.eng - angličtina
    Země vyd.GB - Velká Británie
    Klíč. slovananodiamond ; films ; silicon
    Vědní obor RIVBM - Fyzika pevných látek a magnetismus
    Obor OECDCondensed matter physics (including formerly solid state physics, supercond.)
    Vědní obor RIV – spolupráceFyzikální ústav - Fyzika pevných látek a magnetismus
    Ústav jaderné fyziky - Fyzika pevných látek a magnetismus
    CEPLD15003 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy
    GA14-05053S GA ČR - Grantová agentura ČR
    LM2015056 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy
    Institucionální podporaURE-Y - RVO:67985882 ; FZU-D - RVO:68378271 ; UJF-V - RVO:61389005
    UT WOS000395869500058
    EID SCOPUS85027072108
    DOI10.1039/c6cp08851a
    AnotaceDiamond is proposed as an extraordinary material usable in interdisciplinary fields, especially in optics and photonics. In this contribution we focus on the doping of diamond with erbium as an optically active centre. In the theoretical part of the study based on DFT simulations we have developed two Er-doped diamond structural models with 0 to 4 carbon vacancies in the vicinity of the Er atom and performed geometry optimizations by the calculation of cohesive energies and defect formation energies. The theoretical results showed an excellent agreement between the calculated and experimental cohesive energies for the parent diamond. The highest values of cohesive energies and the lowest values of defect formation energies were obtained for models with erbium in the substitutional carbon position with 1 or 3 vacancies in the vicinity of the erbium atom. From the geometry optimization the structural model with 1 vacancy had an octahedral symmetry whereas the model with 3 vacancies had a coordination of 10 forming a trigonal structure with a hexagonal ring. In the experimental part, erbium doped diamond crystal samples were prepared by ion implantation of Er+ ions using ion implantation fluences ranging from 1 x 10(14) ions per cm(2) to 5 x 10(15) ions per cm(2). The experimental results revealed a high degree of diamond structural damage after the ion implantation process reaching up to 69% of disordered atoms in the samples. The prepared Er-doped diamond samples annealed at the temperatures of 400, 600 and 800 degrees C in a vacuum revealed clear luminescence, where the (110) cut sample has approximately 6-7 times higher luminescence intensity than the (001) cut sample with the same ion implantation fluence. The reported results are the first demonstration of the Er luminescence in the single crystal diamond structure for the near-infrared spectral region
    PracovištěÚstav fotoniky a elektroniky
    KontaktPetr Vacek, vacek@ufe.cz, Tel.: 266 773 413, 266 773 438, 266 773 488
    Rok sběru2018
Počet záznamů: 1  

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