Počet záznamů: 1
Direct detection of the mercury-nitrogen bond in the thymine-Hg-II-thymine base-pair with Hg-199 NMR spectroscopy
- 1.0444868 - ÚOCHB 2016 RIV GB eng J - Článek v odborném periodiku
Dairaku, T. - Furuita, K. - Sato, H. - Šebera, Jakub - Yamanaka, D. - Otaki, H. - Kikkawa, S. - Kondo, Y. - Katahira, R. - Bickelhaupt, F. M. - Guerra, C. F. - Ono, A. - Sychrovský, Vladimír - Kojima, C. - Tanaka, Y.
Direct detection of the mercury-nitrogen bond in the thymine-Hg-II-thymine base-pair with Hg-199 NMR spectroscopy.
Chemical Communications. Roč. 51, č. 40 (2015), s. 8488-8491. ISSN 1359-7345. E-ISSN 1364-548X
Grant CEP: GA ČR GAP205/10/0228
Institucionální podpora: RVO:61388963
Klíčová slova: T-Hg-T * NMR * spin-spin coupling * DFT
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 6.567, rok: 2015
http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc02423d
We have observed the 1-bond Hg-199-N-15 J-coupling ((1)J(Hg-199,N-15) = 1050 Hz) within the Hg-II-mediated thymine-thymine base pair (T-Hg-II-T). This strikingly large (1)J(Hg-199,N-15) is the first one for canonical sp(2)-nitrogen atoms, which can be a sensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration.
Trvalý link: http://hdl.handle.net/11104/0247339
Počet záznamů: 1