Počet záznamů: 1
A new copper(II) Schiff base complex containing asymmetrical tetradentate N.sub.2./sub.O.sub.2./sub. Schiff base ligand: Synthesis, characterization, crystal structure and DFT study
- 1.0448378 - FZÚ 2016 RIV NL eng J - Článek v odborném periodiku
Grivani, G. - Baghan, S.H. - Vakili, M. - Khalaji, A.D. - Tahmasebi, V. - Eigner, Václav - Dušek, Michal
A new copper(II) Schiff base complex containing asymmetrical tetradentate N2O2 Schiff base ligand: Synthesis, characterization, crystal structure and DFT study.
Journal of Molecular Structure. Roč. 1082, Feb (2015), 91-96. ISSN 0022-2860. E-ISSN 1872-8014
Grant CEP: GA ČR(CZ) GA14-03276S
Institucionální podpora: RVO:68378271
Klíčová slova: Schiff-base * copper (II) * complex * single-crystal * thermal decomposition * DFT
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.780, rok: 2015
A new copper (II) Schiff base complex, CuL1, was prepared from the reaction of asymmetrical Schiff base ligand of L1 and Cu(OAC)2 (L1 = salicylidene imino-ethylimino-pentan-2-one). The Schiff base ligand, L1, and its copper (II) complex, CuL1, have been characterized by elemental analysis (CHN) and FT-IR and UV–vis spectroscopy. In addition, 1H NMR was employed for characterization of the ligand. Thermogrametric analysis of the CuL1 reveals its thermal stability and its decomposition pattern shows that it is finally decomposed to the copper oxide (CuO). The crystal structure of CuL1 was determined by the single crystal X-ray analysis. The CuL1 complex crystallizes in the monoclinic system, with space group P21/n and distorted square planar coordination around the metal ion.
Trvalý link: http://hdl.handle.net/11104/0250097
Počet záznamů: 1