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Reductive Alkylation of Amines with Carboxylic Ortho Esters
- 1.0525489 - ÚACH 2021 RIV DE eng J - Článek v odborném periodiku
Kadyrov, Renat - Moebus, K.
Reductive Alkylation of Amines with Carboxylic Ortho Esters.
Advanced Synthesis & Catalysis. Roč. 362, č. 16 (2020), s. 3352-3357. ISSN 1615-4150. E-ISSN 1615-4169
Institucionální podpora: RVO:61388980
Klíčová slova: Alkylation * Amines * Heterogeneous catalysis * Hydrogenation * Ortho esters
Obor OECD: Inorganic and nuclear chemistry
Impakt faktor: 5.837, rok: 2020
Způsob publikování: Open access s časovým embargem
We have demonstrated for the first time that carboxylic ortho esters could be used as an alkylating agent in the reductive alkylation of amines. A variety of amines, including amino acid esters, were alkylated affording mono-alkylated products with high selectivity in practical to high yields using standard heterogeneous catalysts. By applying acyclic ortho esters alkylation was completed at room temperature. (Figure presented.).
Trvalý link: http://hdl.handle.net/11104/0310678
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