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From the Decomposition of Chemical Warfare Agents to the Decontamination of Cytostatics
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SYSNO ASEP 0487621 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název From the Decomposition of Chemical Warfare Agents to the Decontamination of Cytostatics Tvůrce(i) Štengl, Václav (UACH-T) RID, ORCID, SAI
Šťastný, Martin (UACH-T) SAI, RID
Janoš, P. (CZ)
Mazanec, K. (CZ)
Perez-Diaz, J. L. (ES)
Štenglová Netíková, I. R. (CZ)Zdroj.dok. Industrial and Engineering Chemistry Research. - : American Chemical Society - ISSN 0888-5885
Roč. 57, č. 6 (2018), s. 2114-2122Poč.str. 9 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova Chemical warfare agents ; Degradation ; Metal oxide sorbents Vědní obor RIV CA - Anorganická chemie Obor OECD Inorganic and nuclear chemistry Institucionální podpora UACH-T - RVO:61388980 UT WOS 000425473900035 EID SCOPUS 85042130591 DOI 10.1021/acs.iecr.7b04253 Anotace The ability of pilot samples of destructive metal oxide sorbents to decompose a sulfur mustard-type chemical warfare agent into nontoxic products in a nonaqueous solvent was compared with that of the commercial product FAST-ACT. Additionally, samples of the destructive metal oxide sorbents were used to decompose nitrogen mustards, which are used as chemotherapeutic agents, in water, and the results were compared with those of FAST-ACT. All the prepared pilot samples exhibited stoichiometric activities, i.e., the degradation rate expressed by the rate constant, k [s1 , min1 ], and the decomposition efficiencies, which are expressed by the degree of conversion d [%] , higher than those of the comparative commercial product FAST-ACT. Scaling up the sulfur mustard decomposition from the laboratory conditions (reaction volume, 4 L) to quarter-operating (pilot) reaction conditions (reaction volume, 100 L) had a positive effect on the reaction and final product. Pracoviště Ústav anorganické chemie Kontakt Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Rok sběru 2019
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