Počet záznamů: 1
Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins
- 1.0431040 - ÚMCH 2015 RIV US eng J - Článek v odborném periodiku
Strachota, Adam - Rodzen, Krzysztof - Ribot, F. - Trchová, Miroslava - Steinhart, Miloš - Starovoytova, Larisa - Pavlova, Ewa
Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins.
Macromolecules. Roč. 47, č. 13 (2014), s. 4266-4287. ISSN 0024-9297. E-ISSN 1520-5835
Grant CEP: GA ČR GAP108/11/2151
Institucionální podpora: RVO:61389013
Klíčová slova: nanocomposite * hybrid * stannoxane
Kód oboru RIV: CD - Makromolekulární chemie
Impakt faktor: 5.800, rok: 2014
Hybrid organic–inorganic epoxies containing the heavier POSS homologue, n-butylstannoxane dodecamer, incorporated as an inert block, as a linear unit, and as a network junction were prepared. This nanometer-sized inorganic cage is especially attractive because of its chemical reactivity (besides mechanical matrix reinforcement). It can undergo oxidative cross-linking reactions with the matrix, or at elevated temperature in the absence of air, it can oligomerize to larger nanodomains, thus generating additional chemical cross-links. The influences of the bonding situation of the stannoxane cages on the hybrid resins’ morphology, mechanical properties, and on the cages’ chemical activity were studied.
Trvalý link: http://hdl.handle.net/11104/0237025
Počet záznamů: 1