Počet záznamů: 1
Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report)
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SYSNO ASEP 0362869 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report) Tvůrce(i) D'Ulivo, A. (IT)
Dědina, Jiří (UIACH-O) RID, ORCID
Mester, Z. (CA)
Sturgeon, R. E. (CA)
Wang, Q. (CN)
Welz, B. (BR)Celkový počet autorů 6 Zdroj.dok. Pure and Applied Chemistry. - : Walter de Gruyter - ISSN 0033-4545
Roč. 83, č. 6 (2011), s. 1283-1340Poč.str. 58 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova borane complexes ; chemical generation of volatile hydrides (CHG) ; volatile hydrides Vědní obor RIV CB - Analytická chemie, separace CEZ AV0Z40310501 - UIACH-O (2005-2011) UT WOS 000290852100006 DOI 10.1351/PAC-REP-09-10-03 Anotace This report is focused on the rationalization and clarification of fundamental aspects related to CHG: mechanism of hydrolysis of borane complexes; mechanism of hydrogen transfer from the borane complex to the analytical substrate; mechanisms through which the different chemical reaction conditions control the CHG process; and mechanism of action of chemical additives and foreign species. Enhanced comprehension of these different mechanisms and their mutual influence can be achieved in light of the present state of knowledge. This provides the tools to explain the reactivity of a CHG system and contributes to the clarification of several controversial aspects and the elimination of erroneous concepts in CHG. Pracoviště Ústav analytické chemie Kontakt Iveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234 Rok sběru 2012
Počet záznamů: 1