Počet záznamů: 1
Penetrable-Square-Well Fluids: Analytical Study and Monte Carlo Simulations
- 1.0355070 - ÚCHP 2011 RIV US eng J - Článek v odborném periodiku
Fantoni, R. - Giacometti, A. - Malijevský, Alexandr - Santos, A.
Penetrable-Square-Well Fluids: Analytical Study and Monte Carlo Simulations.
Journal of Chemical Physics. Roč. 131, č. 12 (2009), , 124106-1-14. ISSN 0021-9606. E-ISSN 1089-7690
Grant ostatní: MIUR(IT) PRIN-COFIN 2007B57EAB; MEC(ES) FIS2007-60977
Výzkumný záměr: CEZ:AV0Z40720504
Klíčová slova: fisher-widom line * phase-transition * hard-spheres
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 3.093, rok: 2009
We study structural and thermophysical properties of a one-dimensional classical fluid made of penetrable spheres interacting via an attractive square-well potential. Building upon previous exact analytical work in the low-density limit,we propose an approximate theory valid at any density and in the low-penetrable regime. By comparison with specialized Monte Carlo simulations and integral equation theories, we assess the regime of validity of the theory. We investigate the degree of inconsistency among the various routes to thermodynamics and explore the possibility of a fluid-fluid transition. Finally we locate the dependence of the Fisher-Widom line on the degree of penetrability.
Trvalý link: http://hdl.handle.net/11104/0193919
Počet záznamů: 1