Microreactor as Efficient Tool for Light Induced Oxidation Reactions

0436061 - ÚCHP 2015 RIV NL eng J - Článek v odborném periodiku
Hejda, S. - Drhová, Magdalena - Křišťál, Jiří - Buzek, D. - Krystyník, Pavel - Klusoň, Petr
Microreactor as Efficient Tool for Light Induced Oxidation Reactions.
Chemical Engineering Journal. Roč. 255, NOV 1 (2014), s. 178-184. ISSN 1385-8947. E-ISSN 1873-3212
Grant ostatní: GA MŠMT(CZ) MŠk:CZ.1.07/2.2.00/28.0205
Institucionální podpora: RVO:67985858
Klíčová slova: photo microreactor * phthalocyanine * chlorophenol oxidation
Kód oboru RIV: CI - Průmyslová chemie a chemické inženýrství
Impakt faktor: 4.321, rok: 2014

A photo microreactor (PMR) of unique parameters was operated in the degradation of 4-chlorophenol with sulfonated zinc phthalocyanine (ZnPcSmix). This sensitizer was chosen as model homogeneous photocatalyst to evaluate operation parameters and efficiency of the PMR. All reactions were carried out in deuterium oxide to maximize the life-time of the generated singlet oxygen species. In parallel same model oxidations were performed in a laboratory batch system using identical optical arrangements. Both systems were optimized and evaluated with help of kinetic models and rationally compared. It was shown the PMR arrangement revealed much higher process efficacy. Construction details and optimized operating parameters of the PMR are provided and discussed in details.
Trvalý link: http://hdl.handle.net/11104/0239872