Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol

0541903 - ÚFCH JH 2022 RIV GB eng J - Článek v odborném periodiku
Mlekodaj, Kinga - Lemishka, Mariia - Sklenák, Štěpán - Dědeček, Jiří - Tabor, Edyta
Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol.
Chemical Communications. Roč. 57, č. 28 (2021), s. 3472-3475. ISSN 1359-7345. E-ISSN 1364-548X
Grant CEP: GA ČR(CZ) GA17-00742S; GA ČR(CZ) GA19-02901S
Institucionální podpora: RVO:61388955
Klíčová slova: zeolites * oxidation * methane * methanol
Obor OECD: Physical chemistry
Impakt faktor: 6.065, rok: 2021
Způsob publikování: Omezený přístup

Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved dioxygen directly oxidized methane to methanol, which can be released without the aid of an effluent to the gas phase at RT.
Trvalý link: http://hdl.handle.net/11104/0319400