Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

0492682 - ÚACH 2019 RIV GB eng J - Článek v odborném periodiku
Bakardjiev, Mario - Tok, Oleg L. - Růžička, A. - Růžičková, Z. - Holub, Josef - Hnyk, Drahomír - Špalt, Zbyněk - Fanfrlík, Jindřich - Štíbr, Bohumil
Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues.
Dalton Transactions. Roč. 47, č. 32 (2018), s. 11070-11076. ISSN 1477-9226. E-ISSN 1477-9234
Grant CEP: GA ČR(CZ) GA16-01618S
Institucionální podpora: RVO:61388980 ; RVO:61388963
Klíčová slova: carboranes * anion * clusters * cb11h12 * boranes * cage
Obor OECD: Inorganic and nuclear chemistry; Physical chemistry (UOCHB-X)
Impakt faktor: 4.052, rok: 2018

Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C2B8 scaffolding inside the egg-shaped hepta decamethyl sheath, which imparts unusually high air and solvolytic stability to all of these compounds.
Trvalý link: http://hdl.handle.net/11104/0286093


Vědecká data: CCDC, CCDC