X-ray crystallography, electrochemistry, spectral and thermal analysis of some tetradentate schiff base complexes and formation constant measurements

0482872 - FZÚ 2018 RIV US eng J - Článek v odborném periodiku
Asadi, Z. - Savarypour, N. - Dušek, Michal - Eigner, Václav
X-ray crystallography, electrochemistry, spectral and thermal analysis of some tetradentate schiff base complexes and formation constant measurements.
Inorganic and Nano-Metal Chemistry. Roč. 47, č. 11 (2017), s. 1501-1508. ISSN 2470-1556. E-ISSN 2470-1564
Grant CEP: GA ČR(CZ) GA15-12653S
Institucionální podpora: RVO:68378271
Klíčová slova: X-ray crystallography * transition metal Schiff base complexes * thermogravimetry * electrochemistry * formation constant measurements
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)

A series of new transition metal Schiff base complexes was synthesized via the reaction of H2L (N,N0-bis(naphthylidene)-2-aminobenzylamine) with the transition metals and characterized by elemental analysis, 1HNMR, FT-IR, UV-Vis spectroscopy, thermogravimetric analysis(TG) and in selected cases by X-ray crystallography. Thermodynamics of complex formation, electrochemistry of the metal Schiff base complexes and kinetic aspects of thermal decomposition of the complexes were also studied. Cyclic voltammogram of the complexes in acetonitrile was done to evaluate the redox behavior of the complexes.

Trvalý link: http://hdl.handle.net/11104/0283316