Influence of the Alkyl Side Chain Length on the Thermophysical Properties of Chiral Ionic Liquids with a (1R,2S,5R)-(–)-Menthol Substituent and Data Treatment by Means of Mathematical Gnostics.

0476320 - ÚCHP 2018 RIV NL eng J - Článek v odborném periodiku
Andresová, Adéla - Bendová, Magdalena - Schwarz, Jaroslav - Wagner, Zdeněk - Feder-Kubis, J.
Influence of the Alkyl Side Chain Length on the Thermophysical Properties of Chiral Ionic Liquids with a (1R,2S,5R)-(–)-Menthol Substituent and Data Treatment by Means of Mathematical Gnostics.
Journal of Molecular Liquids. Roč. 242, SEP 2017 (2017), s. 336-348. ISSN 0167-7322. E-ISSN 1873-3166
Grant CEP: GA MŠMT(CZ) 7AMB14PL005
Grant ostatní: NSC(PL) 2011/01/B/ST5/06659
Institucionální podpora: RVO:67985858
Klíčová slova: chiral ionic liquids * thermophysical properties * mathematical gnostics
Obor OECD: Physical chemistry
Impakt faktor: 4.513, rok: 2017

A comprehensive physico-chemical characterization of the chiral ionic liquids of a 3-alkyl-1-[(1R,2S,5R)-(–)-menthoxymethyl]imidazolium bis(trifluoromethylsulfonyl)imides homologous series with a linear alkyl substituent was carried out experimentally. Refractive index, density, speed of sound, and isobaric heat capacity were measured as a function of temperature at atmospheric pressure and analyzed by methods based on mathematical gnostics. A robust linear regression along a gnostic influence function was used to optimize parameters of the relationships used in this work and to estimate the changing nanosegregation in the studied ionic liquid series by finding the Critical Alkyl Length Size (CALS) from heat capacity data. In addition, we propose the use of the marginal analysis to assess the quality of the measured data as an alternative to the estimate of the measurement uncertainty.
Trvalý link: http://hdl.handle.net/11104/0273440