0382579 - ÚACH 2013 RIV NL eng J - Článek v odborném periodiku
Langecker, Jens - Fejfarová, Karla - Dušek, Michal - Rentsch, D. - Baše, Tomáš
Carbon-substituted 9,12-dimercapto-1,2-dicarba-closo-dodecaboranes via a 9,12-bis(methoxy-methylthio)-1,2-dicarba-closo-dodecaborane precursor.
Polyhedron. Roč. 45, č. 1 (2012), s. 144-151. ISSN 0277-5387. E-ISSN 1873-3719
Grant CEP: GA ČR GAP205/10/0348
Výzkumný záměr: CEZ:AV0Z40320502; CEZ:AV0Z10100521
Klíčová slova: carborane * dicarba-closo-dodecaborane * dimercapto-carborane * dimercapto-dicarba-closo-dodecaborane * dithiolcarborane * protecting group * substitution * surfactant
Kód oboru RIV: CA - Anorganická chemie; BM - Fyzika pevných látek a magnetismus (FZU-D)
Impakt faktor: 1.813, rok: 2012

Dithiolated derivatives of 1,2-dicarba-closo-dodecaboranes are common ligands to be used for self-assembling monolayers, nanoparticles or transition complexes due to their robust molecular structure. The 9,12-dimercapto-1,2- dicarba-closo-dodecaborane, a derivative with two SH-groups in adjacent positions, is an interesting unit for the preparation of derivatives additionally functionalized in positions one and two. In this contribution, we report a convenient synthesis of 1,2-disubstituted 9,12-dimercapto-1,2-dicarba- closo-dodecaboranes starting from the 9,12-dimercapto-1,2-dicarba-closo- dodecaboranes with SH groups protected using methoxy-methyl (MOM) groups. All compounds are well characterized via HiRes-mass spectroscopy, 1H, 13C and 11B NMR-spectroscopy and IR spectroscopy. The precursor 9,12-bis(methoxy-methylthio)-1,2-dicarba-closo-dodecaborane was additionally characterized with X-ray-structural analysis.
Trvalý link: http://hdl.handle.net/11104/0212763