Hydrothermal conversion of cerium oxalate to CeO.sub.2./sub.: a parade of oxalate and water coordination modes

0585215 - FZÚ 2025 RIV GB eng J - Článek v odborném periodiku
Assi, N. - Lahoud, C. - Brázda, Petr - Zákutná, D. - Rainer, D. N. - Hraníček, J. - Rohlíček, Jan - Tyrpekl, V.
Hydrothermal conversion of cerium oxalate to CeO₂: a parade of oxalate and water coordination modes.
New Journal of Chemistry. Roč. 48, č. 3 (2023), s. 1071-1075. ISSN 1144-0546. E-ISSN 1369-9261
Grant CEP: GA ČR(CZ) GX21-05926X; GA MŠMT(CZ) EF16_019/0000760
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Výzkumná infrastruktura: CzechNanoLab - 90110; CzechNanoLab II - 90251
Institucionální podpora: RVO:68378271
Klíčová slova: oxalate salts * hydrothermal conversion * crystal structure * X-ray diffraction * SEM * TEM * TGA
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 3.3, rok: 2022
Způsob publikování: Open access

Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f-elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands.
Trvalý link: https://hdl.handle.net/11104/0352979