Unveiling the topology of partially disordered micro-crystalline nitro-perylenediimide with X-aggregate stacking: an integrated approach

0585125 - FZÚ 2025 RIV GB eng J - Článek v odborném periodiku
Mathew, R. - Mazumder, A. - Kumar, P. - Matula, J. - Mohamed, S. - Brázda, Petr - Hariharan, M. - Thomas, B.
Unveiling the topology of partially disordered micro-crystalline nitro-perylenediimide with X-aggregate stacking: an integrated approach.
Chemical Science. Roč. 15, č. 2 (2024), s. 490-499. ISSN 2041-6520. E-ISSN 2041-6539
Grant CEP: GA ČR(CZ) GX21-05926X; GA MŠMT(CZ) EF16_019/0000760
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Výzkumná infrastruktura: CzechNanoLab - 90110; CzechNanoLab II - 90251
Institucionální podpora: RVO:68378271
Klíčová slova: organic molecules * nitro-perylenediimide * solid-state DMR * 3D electron diffraction
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 8.4, rok: 2022
Způsob publikování: Open access

Profound knowledge of the molecular structure and supramolecular organization of organic molecules is essential to understand their structure–property relationships. Herein we demonstrate the packing arrangement of partially disordered nitro-perylenediimide (NO2-PDI), revealing that the perylenediimide units exhibit an X-shaped packing pattern. The packing of NO2-PDI is derived using a complementary approach that utilises solid-state NMR (ssNMR) and 3D electron diffraction (3D ED) techniques.
Trvalý link: https://hdl.handle.net/11104/0352858