A novel atmospheric pressure glow discharge system for sensitive determination of As, Sb, and Se by optical emission spectrometry following their hydride generation

0582929 - ÚIACH 2025 RIV NL eng J - Článek v odborném periodiku
Greda, K. - Kratzer, Jan - Vlčková, Nikol - Pohl, P.
A novel atmospheric pressure glow discharge system for sensitive determination of As, Sb, and Se by optical emission spectrometry following their hydride generation.
Spectrochimica Acta Part B: Atomic Spectroscopy. Roč. 213, FEB (2024), č. článku 106879. ISSN 0584-8547. E-ISSN 1873-3565
Grant CEP: GA ČR(CZ) GF23-05974K
Institucionální podpora: RVO:68081715
Klíčová slova: atmospheric pressure glow discharge * hydride atomization * optical emission spectrometry
Obor OECD: Analytical chemistry
Impakt faktor: 3.3, rok: 2022
Způsob publikování: Omezený přístup

Hydride generation (HG) was combined with an atmospheric pressure glow discharge (APGD), sustained in a completely novel system, to sensitively determine As, Sb, and Se by optical emission spectrometry (OES). The detection limits (DLs) of As, Sb, and Se were 0.6, 0.14, and 1.2 µg L-1, respectively. The accuracy of HG-APGD OES was verified using a recovery test, and proved by high agreement between spiked and measured concentrations of As, Sb, and Se in mineral and tap water samples with reaching recoveries within the range of 96-103%.
Trvalý link: https://hdl.handle.net/11104/0350972