Azeotropic Behavior of the 2-Methylpropan-2-ol + water + 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide System.

0581686 - ÚCHP 2024 RIV HR eng J - Článek v odborném periodiku
Pavlíček, Jan - Bogdanić, Grozdana - Wichterle, Ivan
Azeotropic Behavior of the 2-Methylpropan-2-ol + water + 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide System.
Chemical and Biochemical Engineering Quarterly. Roč. 37, č. 4 (2023), s. 223-227. ISSN 0352-9568. E-ISSN 1846-5153
Grant CEP: GA ČR(CZ) GA20-06825S
Institucionální podpora: RVO:67985858
Klíčová slova: alcohol-water system * azeotropy * correlation * ionic liquid
Obor OECD: Physical chemistry
Impakt faktor: 1.5, rok: 2022
Způsob publikování: Open access
http://silverstripe.fkit.hr/cabeq/past-issues/article/2219

Vapor-liquid equilibrium data were measured isothermally in the near-azeotropic region of the 2-methylpropan-2-ol + water + 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide system at 333.15, 343.15, and 353.15 K. The data were processed using a recently developed method based on a small number of experiments that provides a complete thermodynamic description of the azeotropic behavior. The parameters of the third-order Redlich-Kister equation were correlated with the ionic liquid concentration to determine an analytical dependence of both the azeotropic composition and the pressure.
Trvalý link: https://hdl.handle.net/11104/0349877