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Graphitic carbon nitride/xylene soot metal-free nanocomposites for photocatalytic degradation of organic compounds
- 1.0581422 - ÚCHP 2024 RIV NL eng J - Článek v odborném periodiku
Smýkalová, A. - Slowik, G. - Koštejn, Martin - Kawuloková, M. - Foniok, K. - Novák, V. - Praus, P.
Graphitic carbon nitride/xylene soot metal-free nanocomposites for photocatalytic degradation of organic compounds.
Diamond and Related Materials. Roč. 139, NOV 2023 (2023), č. článku 110434. ISSN 0925-9635. E-ISSN 1879-0062
Institucionální podpora: RVO:67985858
Klíčová slova: g-c3n4 * water * composites * decomposition
Obor OECD: Chemical process engineering
Impakt faktor: 4.1, rok: 2022
Způsob publikování: Open access s časovým embargem
Graphitic carbon nitride and soot (g-C3N4/soot) metal-free nanocomposites were synthesized by a simple one-pot thermal synthesis from mixtures of dicyandiamide with different volumes of xylene. The soot nanoparticles of 17.7 +/- 1.7 nm in size were observed on the g-C3N4 surface.The band gap energies of the synthesized nanocomposites decreased from 2.65 eV to 2.53 eV with the increasing content of soot nanoparticles. The photocatalytic activity of the g-C3N4/soot nanocomposites to degrade phenol, ofloxacin, and ampicillin under the LED irradiation of 420 nm was investigated. Time-resolved photoluminescence measurements, electrochemical impedance spectroscopy, and trapping experiments indi-cated that photoinduced electrons were accumulated in the soot particles, reacted with oxygen forming superoxide radicals, which decomposed the organic compounds. The degradation efficiency decreased in the sequence ofloxacin > ampicillin > phenol. The g-C3N4/soot nanocomposites were investigated for the photocatalytic degradation of organic compounds for the first time.
Trvalý link: https://hdl.handle.net/11104/0349674
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