Počet záznamů: 1
Fine-tuning NHC ligands for ruthenium-catalyzed hydrogenation of carboxylic esters to alcohols
- 1.0574112 - ÚACH 2024 RIV NL eng J - Článek v odborném periodiku
Kadyrov, Renat
Fine-tuning NHC ligands for ruthenium-catalyzed hydrogenation of carboxylic esters to alcohols.
Journal of Catalysis. Roč. 426, OCT (2023), s. 173-177. ISSN 0021-9517. E-ISSN 1090-2694
Institucionální podpora: RVO:61388980
Klíčová slova: Alcohols * Carbene ligands * Homogeneous catalysis * Hydrogenation * Ruthenium
Obor OECD: Inorganic and nuclear chemistry
Impakt faktor: 7.3, rok: 2022
Způsob publikování: Omezený přístup
https://doi.org/10.1016/j.jcat.2023.07.006
An efficient and simple catalytic system has been developed for hydrogenation of carboxylic esters. Combination of commercially available Ru-salts and simple imidazolium salts bearing N-cyclohexyl, N-cycloheptyl and N-cyclooctyl substituents enable reduction of esters to alcohols at 40 °C and 40 bar of hydrogen pressure. The reaction protocol offers a practical access to alcohols using an easy operational setup.
Trvalý link: https://hdl.handle.net/11104/0344465
Počet záznamů: 1