Spectroelectrochemical study on catecholase catalytic activity of selected mononuclear copper(II) complexes

0573654 - ÚFCH JH 2024 RIV GB eng J - Článek v odborném periodiku
Kocábová, Jana - Sýs, M. - Klikarová, J. - Novák, M. - Bártová, M. - Jirásko, R. - Tarábková, Hana - Sokolová, Romana - Mikysek, T.
Spectroelectrochemical study on catecholase catalytic activity of selected mononuclear copper(II) complexes.
Electrochimica acta. Roč. 463, SEP 2023 (2023), č. článku 142854. ISSN 0013-4686. E-ISSN 1873-3859
Grant CEP: GA ČR(CZ) GA19-03160S
Institucionální podpora: RVO:61388955
Klíčová slova: Mononuclear copper(II) complexes * Tyrosinase biomimetic catalyst * Catecholase-like activity
Obor OECD: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Impakt faktor: 6.6, rok: 2022
Způsob publikování: Omezený přístup

In general, a great majority of artificial enzymes provides a low substrate selectivity and negligible catalytic activity in aqueous media compared to enzymes isolated from living organisms [1]. Thus, they cannot be used as biorecognition agents in the configuration of long-life biosensors potentially applicable in clinical analysis. This problem can be solved by the synthesis of new metallo-complexes and characterization of their catalytic activity. The existence of several biomimetic sensors utilizing the artificial enzymes suggests one that this new generation of portable analytical devices will play an important role in analysis [2].
Trvalý link: https://hdl.handle.net/11104/0344044