Thermodynamics and crystal structures of krautite, Mn[AsO.sub.3./sub.(OH)]⋅H.sub.2./sub.O, koritnigite, Zn[AsO.sub.3./sub.(OH)]⋅H.sub.2./sub.O, and cobaltkoritnigite, Co[AsO.sub.3./sub.(OH)]⋅H.sub.2./sub.O

0572974 - FZÚ 2024 RIV GB eng J - Článek v odborném periodiku
Majzlan, J. - Plášil, Jakub - Dachs, E.
Thermodynamics and crystal structures of krautite, Mn[AsO₃(OH)]⋅H₂O, koritnigite, Zn[AsO₃(OH)]⋅H₂O, and cobaltkoritnigite, Co[AsO₃(OH)]⋅H₂O.
Mineralogical Magazine. Roč. 87, č. 2 (2023), s. 194-203. ISSN 0026-461X. E-ISSN 1471-8022
Grant CEP: GA MŠMT(CZ) EF16_019/0000760
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Institucionální podpora: RVO:68378271
Klíčová slova: krautite * koritnigite * thermodynamics * crystal structures * hydrogen bonding
Obor OECD: Mineralogy
Impakt faktor: 2.7, rok: 2022
Způsob publikování: Open access

Synthetic samples of Mn[AsO3(OH)].H2O, koritnigite, Zn[AsO3(OH)].H2O, and cobaltkoritnigite, Co[AsO3(OH)].H2O, were used for calorimetric experiments. For krautite and koritnigite, single-crystal X-ray diffraction was used to determine positions of all atoms, including the H atoms. These data allowed to determine the hydrogen-bond network and the function of H2O molecules in these structures.
Trvalý link: https://hdl.handle.net/11104/0343505