Hot Corrosion Behavior of TWAS and HVOF NiCr-Based Coatings in Molten Salt

0572070 - ÚFP 2024 RIV CH eng J - Článek v odborném periodiku
Lencová, K. - Netrvalová, M. - Vostřák, M. - Lukáč, František - Mušálek, Radek - Česánek, Z. - Houdková, Š.
Hot Corrosion Behavior of TWAS and HVOF NiCr-Based Coatings in Molten Salt.
Materials. Roč. 16, č. 4 (2023), č. článku 1712. E-ISSN 1996-1944
Institucionální podpora: RVO:61389021
Klíčová slova: gravimetric method * hot corrosion * hvof * molten salt * NiCr-based coating * Raman spectroscopy * twas * X-ray diffraction
Obor OECD: Coating and films
Impakt faktor: 3.4, rok: 2022
Způsob publikování: Open access
https://www.mdpi.com/1996-1944/16/4/1712

In order to extend the life of boilers by applying an anti-corrosion coating without the need to dismantle them, it is advisable to find coatings that can be applied using cheaper and portable techniques, such as Twin Wire Arc Spray technology (TWAS). In this study, we compare selected NiCr-based coatings and two uncoated steel substrates (steel 1.7715 and 1.4903). Two coatings, Cr3C2 25% NiCr and Hastelloy C-276 are deposited using High velocity oxygen-fuel technology (HVOF) and three coatings, NiCrTi, NiCrMo, and Inconel 625, are deposited using TWAS. In addition to the corrosion weight gain during 50 cycles of loading in an 18% Na2SO4 and 82% Fe2(SO4)3 salt environment at 690 °C evaluated using the gravimetric method, the microstructure and phase composition of the coatings were analyzed on the samples after the exposure in order to compare the properties and gain a deeper understanding of the corrosion kinetics. Coating cross-sections and free-surfaces were observed with a scanning electron microscope (SEM) with an energy-dispersive (EDX) system. The phase composition was investigated using X-ray diffraction (XRD) and Raman spectroscopy. No significant differences were observed between the TWAS and HVOF coating methods for the coatings compared. Due to the similar corrosion products found on all coatings, a very effective corrosion protective layer was formed on the surface, forming a barrier between the corrosive environment and the coating regardless of the used deposition technology. Therefore, for industrial use on the inner surface of coal-fired boilers we recommend NiCrTi, NiCrMo, or Inconel coatings prepared with the more cost-effective and portable TWAS technology.
Trvalý link: https://hdl.handle.net/11104/0342906