0571005 - ÚFCH JH 2024 RIV CH eng J - Článek v odborném periodiku
Civiš, Svatopluk - Pastorek, Adam - Ferus, Martin - Yurchenko, S. N. - Boudjema, N.-I.
Infrared Spectra of Small Radicals for Exoplanetary Spectroscopy: OH, NH, CN and CH: The State of Current Knowledge.
Molecules. Roč. 28, APR 2023 (2023), č. článku 3362. ISSN 1420-3049. E-ISSN 1420-3049
Grant CEP: GA MŠMT EF16_019/0000778; GA ČR(CZ) GA21-11366S
GRANT EU: European Commission(XE) 883830
Grant ostatní: ERDF(CZ) CZ.02.1.01/0.0/0.0/16_019/0000778
Institucionální podpora: RVO:61388955
Klíčová slova: radicals * spectroscopy * infrared spectra
Obor OECD: Physical chemistry
Impakt faktor: 4.2, rok: 2023 ; AIS: 0.676, rok: 2023
Způsob publikování: Open access
DOI: https://doi.org/10.3390/molecules28083362

In this study, we present a current state-of-the-art review of middle-to-near IR emission spectra of four simple astrophysically relevant molecular radicals—OH, NH, CN and CH. The spectra of these radicals were measured by means of time-resolved Fourier transform infrared spectroscopy in the 700–7500 cm−1 spectral range and with 0.07–0.02 cm−1 spectral resolution. The radicals were generated in a glow discharge of gaseous mixtures in a specially designed discharge cell. The spectra of short-lived radicals published here are of great importance, especially for the detailed knowledge and study of the composition of exoplanetary atmospheres in selected new planets. Today, with the help of the James Webb telescope and upcoming studies with the help of Plato and Ariel satellites, when the investigated spectral area is extended into the infrared spectral range, it means that detailed knowledge of the infrared spectra of not only stable molecules but also the spectra of short-lived radicals or ions, is indispensable. This paper follows a simple structure. Each radical is described in a separate chapter, starting with historical and actual theoretical background, continued by our experimental results and concluded by spectral line lists with assigned notation.

Trvalý link: https://hdl.handle.net/11104/0342327