Počet záznamů: 1  

Polymer brushes based on N-methacryloxysuccinimide as platform for versatile post-polymerization modification

  1. 1.
    0568552 - ÚMCH 2024 RIV NL eng J - Článek v odborném periodiku
    Sivkova, Radoslava - Svoboda, Jan - Pánek, Jiří - Appelhans, D. - Pop-Georgievski, Ognen
    Polymer brushes based on N-methacryloxysuccinimide as platform for versatile post-polymerization modification.
    Progress in Organic Coatings. Roč. 178, May (2023), č. článku 107447. ISSN 0300-9440. E-ISSN 1873-331X
    Grant CEP: GA ČR(CZ) GA20-07313S
    Grant ostatní: AV ČR(CZ) StrategieAV21/26; AV ČR(CZ) MSM200501903
    Program: StrategieAV; Program na podporu mezinárodní spolupráce začínajících výzkumných pracovníků
    Institucionální podpora: RVO:61389013
    Klíčová slova: polymer brush * surface-initiated polymerization * active ester monomer
    Obor OECD: Physical chemistry
    Impakt faktor: 6.6, rok: 2022
    Způsob publikování: Omezený přístup
    https://www.sciencedirect.com/science/article/pii/S0300944023000437?via%3Dihub

    In this contribution we present a method for the surface-initiated atom-transfer radical polymerization of active esters based on N-methacryloxysuccinimide and post-polymerization modification in mild conditions. The obtained active ester brushes show quantitative conversion under amidation conditions with various primary amines, including 1-amino-2-propanol, fluorine containing amines and amine-containing fluorophores. Amidation reaction with propargyl amine offers the possibility to introduce a second functionality in the homopolymer brushes. This widens the ability of polymer analogous reactions with functionalized compounds. The effectiveness of the amidation reaction was deeply studied utilizing spectroscopic ellipsometry, infrared reflection-absorption and X-ray photoelectron spectroscopies, contact angle goniometry and surface energy analysis. As validated by functionalized homopolymer brushes, hierarchical block copolymer brushes containing active ester monomer units also undergo quantitative conversion with primary amines. Furthermore, resulting polymer brushes containing fluorophores were studied by fluorescent microscopy to further investigate their film structure and homogeneity.
    Trvalý link: https://hdl.handle.net/11104/0340084

     
     
Počet záznamů: 1  

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